TNT

TNT (trinitrotoluene, tol, TNT) is the primary brisant high explosive used for demolition operations and filling munitions; as a rule, it is a crystalline substance ranging from light yellow to light brown in color, with a bitter taste.

TNT demolition block weighing 200 grams
TNT demolition block weighing 200 grams
TNT demolition block weighing 200 grams

Characteristics of TNT

First obtained
1866
Start of use
1902
Formula
C6H2(NO2)3CH3
Starting materials
toluene, mixture of nitric and sulfuric acids
Structure
crystalline substance
Color
yellow
Taste
bitter
Combustion
burns with a yellow flame and soot; combustion may transition to an explosion
Interaction with metals
does not react with metals
Solubility in water
non-hygroscopic, insoluble
TNT equivalent
1
Sensitivity
low sensitivity
Impact sensitivity
4-8%
Density
1600 kg/m3
Detonation velocity
6900 m/s
Specific energy of explosive transformation
4.2 kJ/kg
Explosive strength
290 cm3
Brisance
16 mm
Specific volume of explosion products
0.87 m3/kg
Guaranteed shelf life
decades

TNT is non-hygroscopic and practically insoluble in water. In industry it is produced in the form of powder (powdered TNT), small flakes (flaked TNT), or granules (granulated TNT). In the Armed Forces of Ukraine, TNT is used in the form of pressed blocks weighing 400, 200, and 75 grams. TNT melts without decomposition at a temperature of about +81 ºC. In open air, TNT burns with a yellow flame and heavy soot, without exploding. Combustion in large quantities (50 kg or more), or in a confined environment, may transition to detonation. TNT has low sensitivity to impact, friction, and thermal effects. Pressed and cast TNT does not explode or ignite when struck by an ordinary rifle bullet and does not chemically react with metals. The sensitivity of TNT to detonation depends on its state. Pressed and powdered TNT detonates reliably from a No. 8 blasting cap; cast, flaked, and granulated TNT detonates only from a booster made of pressed TNT or another brisant high explosive. The chemical stability of TNT is fairly high; prolonged heating at temperatures up to +130 ºC or prolonged immersion in water causes little change in its explosive properties. Under the influence of sunlight, TNT undergoes physicochemical transformations accompanied by color changes and a certain increase in sensitivity to external effects.

TNT demolition block weighing 75 grams
TNT demolition block weighing 75 grams
TNT demolition block weighing 75 grams
TNT demolition block weighing 400 grams
TNT demolition block weighing 400 grams
TNT demolition block weighing 400 grams
TNT demolition blocks in standard packaging
TNT demolition blocks in standard packaging
TNT demolition blocks in standard packaging
Crushed TNT, likely taken from anti-tank mines
Crushed TNT, likely taken from anti-tank mines
Crushed TNT, likely taken from anti-tank mines